Syntheses and high temperature phase transformations of alunite-Natroalunite solid solution series.

Solid Phase Syntheses of Oligoureas

Isocyanates 7 were formed from monoprotected diamines 3 or 6, which in turn can be easily prepared from commercially available N-BOCor N-FMOC-protected amino acid derivatives. Isocyanates 7, formed in situ, could be coupled directly to a solid support functionalized with amine groups or to amino acids anchored on resins using CH2Cl2 as solvent and an 11 h coupling time at 25 °C. Such couplings ...

High Temperature Behavior of Dual Phase Steels

Dual phase steels with different martensite volume fraction and morphology were tensile tested at a temperature range of 25 to 5500C. Stress-strain curves of all steels showed serration flow at temperatures of 250 and 3500C, and smooth flow at the other temperatures. Both yield and ultimate tensile strengths increased with increasing testing temperature up to about 450<sup...

Efficient Syntheses of 1,2,3-Triazoloamide Derivatives Using Solid- and Solution-Phase Synthetic Approaches.

Efficient synthetic routes for the preparation of secondary and tertiary 1,2,3-triazoloamide derivatives were developed. A secondary α-1,2,3-triazoloamide library was constructed and expanded by a previously developed solid-phase synthetic route and a tertiary 1,2,3-triazoloamide library was constructed by a parallel solution-phase synthetic route. The synthetic routes rely on amide formation w...

Kinetics and morphological instabilities of stressed solid-solid phase transformations.

An atomistic model of the growth kinetics of stressed solid-solid phase transformations is presented. Solid phase epitaxial growth of (001) Si was used for comparison of new and prior models with experiments. The results indicate that the migration of crystal island ledges in the growth interface may involve coordinated atomic motion. The model accounts for morphological instabilities during st...

Phase Transformations Preparation of Solid State Materials